Cooling Mali’s volcanism
Lightning links to ozone over Africa

Cooling Mali’s volcanism

In the Timbuktu region south of the Sahara in Mali, patches of ground have been smoking for many decades. Plumes of water vapor and carbon dioxide escape from red-hot holes and fissures in the ground. In April 2001, the inferno below the surface began to radiate outwards, scorching tree roots and leaving a trail of burnt soils and fallen trees. Over the following 10 months, the subsurface fires consumed more than 500 acres of richly vegetated land.

A local citizen watches smoke blowing out of fumaroles near Lac Faguibine, west of Timbuktu, Mali. A team of Norwegian geologists found that subsurface peat fires, not magma intrusions, fuel the fumaroles. Photo by Henrik Svensen, Volcanic Basin Petroleum Research.

Theodore Monod, a French humanist and scholar, first characterized the smoking holes, or fumaroles, in 1961. He concluded they were signs that the region had become volcanically active. Magma bubbling up from depth fueled the fumaroles. Local officials feared the recent increase in activity foretold a disastrous volcanic eruption. The Ministry of Mines, Energy and Water in Mali asked a group of Norwegian geologists who specialize in volcanic basins to visit the sites and assess the hazard. According to their report in the August Geology, in just four days, the geologists collected the data they needed to overturn — and substantially reduce — the calculated risk for the region. The authors found that the spontaneous combustion of buried peat layers, not migrating magma, caused the subsurface fires.

In his original survey of the Lac Faguibine region, about 50 miles west of Timbuktu, Monod found dikes mixed in with the soils around the fumaroles. He suggested the dikes were basaltic and hosted the mineral nepheline, which could only have come from magma. In the early 1990s, French geologists built a geologic model of the region that supported the volcanism hypothesis by indicating that a huge and dense mass, likely magma, sat just 2 kilometers beneath the surface. They argued that a major east-west trending lineament had recently reactivated, and that the energy from the pull-apart tectonics drove the magma intrusion. Later, in 2000, a group of geologists from Sonatrach, an Algerian oil company, surveyed the region and past research; they concluded that the fumaroles did indeed result from volcanism — fueling local concerns of imminent disaster.

When the Norwegian team arrived in Mali, they expected to find signs of volcanism. Digging a 2.5-meter-deep trench at Haribibi, one of the sites with fissures and escaping smoke, they found a thin layer of peat burning just 60 centimeters below the surface. The temperature in the peat layer exceeded 800 degrees Celsius, but dropped back down to cool background levels just 70 centimeters farther down. “Then we had two possibilities,” says lead author of the Geology paper Henrik Svensen, a geologist at the University of Oslo in Norway. “The burning peat layer was the only source of the heat anomalies, or the peat layer could have been ignited by, let’s say, magma at 1,000 degrees Celsius. In the latter case, magma would have to be present 1 to 1.5 meters below the surface.” But they found no signs of magma.

A close-up of one of the fumaroles shows the fire beneath. White mineral sublimates have precipitated out of escaping gases, accumulating around the edges of the hole. Photo by Henrik Svensen, Volcanic Basin Petroleum Research.

The group concluded that microbial decomposition of organic matter in the peat had likely generated enough heat to set the peat on fire. The impacted sites sit in a dried-out lake basin; the old sediments provide the rich organic material needed to stimulate high rates of microbial decomposition. “Burning peat is a relatively common phenomenon,” Svensen says. Subsurface peat fires burn in parts of Botswana, and surface peat fires occur frequently in the United States and South Africa, he adds.
During the rainy season, the Niger River occasionally rises enough to flood the Lac Faguibine region. Those floods have historically quelled the subsurface heat, which matches the pattern expected from peat fires, not magma intrusions, Svensen says.

The volcanism hypothesis persisted for over 40 years largely because Monod was a legendary figure and a well-respected scientist, Svensen says. The minerals that Monod initially argued formed from magma intrusion could just have easily formed from the heating and melting of minerals in the burning peat, he adds.

Glenn B. Stracher, a geologist at East Georgia College in Swainsboro, Ga., who studies subsurface coal fires, agrees. “Although lavas derived from coal fires are documented in the geologic literature, people don’t usually consider peat or coal combustion as the heat source for generating molten and subsequently igneous rock,” Stracher says.

The several thousand people living in villages and nomad camps in the Lac Faguibine region no longer face the prospect of a volcanic eruption, says co-author Dag Dysthe, a physicist at the University of Oslo. But the peat fires still pose potential health and environmental risks. By burning tree and grass roots, the fires increase the rate of desertification at the fringes of the Sahara, Dysthe says. Also, Svensen adds, the fires are extremely difficult to put out, and the gases emanating from the fumaroles and fissures may contain hydrochloric acid and sulfur dioxide, both toxic.

Greg Peterson

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Lightning links to ozone over Africa

About five years ago, atmospheric scientists studying ozone concentrations over equatorial Africa and the southern hemisphere of the tropical Atlantic came across a puzzling situation. They expected to see high levels of ozone north of the equator, where subsistence farmers, as part of a traditional annual practice, had set massive fires to clear the savannas of grass in preparation for planting. Burning such great quantities of biomass releases large amounts of carbon monoxide and chemically reactive nitrogen oxides (NOx), which are important ingredients in forming ozone. But the researchers’ instruments told a different story — ozone concentrations were higher south of the equator, where no fires were burning at the time.

With no apparent source for ozone formation in the southern hemisphere, “people in the atmospheric research community were scratching their heads, trying to work out where the ozone was coming from,” says David Edwards of the National Center for Atmospheric Research in Boulder, Colo. “How do these pollutants move from the northern hemisphere to the southern hemisphere?” This was especially perplexing given that the pollutants would have traveled across the intertropical convergence zone, a well-known atmospheric barrier to movement of air masses between hemispheres in the tropics.

The vertical column of carbon monoxide (CO) for January 2001, measured by the MOPITT instrument on NASA’s Terra satellite. The reds show the highest levels of CO and blues show the lowest levels. The white areas show where no data were collected due to persistent cloud cover. The pollution plumes in the atmosphere over northwestern Africa that extend westward well out over the Atlantic Ocean occur as a result of the agricultural fires that are set at this time of the year. Courtesy of Journal of Geophysical Research.

Unfortunately, the technology needed to solve this so-called “ozone paradox” was still in development. Measurements of gases using weather balloons and instruments on aircraft could not provide a broad enough picture of the region, and satellite-based instruments that could make accurate concentration measurements in the lower atmosphere were only just coming online.

In the end, the coordinated efforts of four separate satellites, each responsible for a different measurement — carbon monoxide concentrations, nitrogen dioxide (NO2) concentrations, the number of fires burning and the number of lightning strikes in the region — helped to find a possible solution to the paradox. The combined data suggests that high lightning activity in the southern hemisphere is the culprit. Lightning provides the energy needed for the reaction of nitrogen and oxygen in the atmosphere to form nitrogen oxide compounds, leading to subsequent reactions to produce ozone.

Edwards is the project leader for one of these satellites, the Terra Measurement of Pollution in the Troposphere (Terra/
MOPITT) satellite — a joint Canadian-United States venture that uses thermal and near-infrared radiation to measure carbon monoxide concentrations in the lower atmosphere. MOPITT can sample virtually the entire surface of Earth in only three days.

The MOPITT group teamed up with researchers from the second European Remote Sensing Satellite Global Ozone Monitoring Experiment, which measures nitrogen dioxide concentrations; the Tropical Rainfall Measuring Mission Visible and Infrared Scanner, which maps ground fires; and the TRMM Lightning Imaging Sensor, which counts lightning strikes by measuring cloud brightness. After feeding their data into a mathematical model, the researchers were able to predict where ozone was likely to form.

For the study reported in the April 17, 2003, issue of Journal of Geophysical Research, Edwards and his colleagues analyzed data from January 2001, a month when farmers in the northern hemisphere of Africa traditionally set their ground-clearing fires. Carbon monoxide was present in high concentrations in regions above the fires, but it did not flow south of the equator — blocked by the intertropical convergence zone, as expected. In the southern hemisphere, very few fires were present, but the number of lightning strikes was substantial. Correlating lightning strikes with nitrogen dioxide concentrations indicated clearly that lightning was the cause of the high levels of ozone in the southern hemisphere of Africa at this time of year.

The lightning flash mean count rate detected by the TRMM/LIS instrument for January 2001. The lightning activity over southern Africa and South America produces large amounts of reactive nitrogen oxides in the atmosphere that are later involved in ozone formation in the lower part of the atmosphere. The prevailing winds then deposit this ozone over the southern tropical Atlantic, south of the region of high pollution caused by the fires. [Courtesy Journal of Geophysical Research.]

“Satellite measurement of carbon monoxide brings new data to bear on the problem,” says Anne Thompson of the Goddard Space Flight Center, who coined the term “ozone paradox” while analyzing atmospheric data she collected on the Aerosols99 oceanographic research voyage in January and February of 1999. “What Edwards has done is to carry the data analysis one or two steps further than was previously possible, which is a great accomplishment,” she says.

The new technology that provided insight into the conundrum is as important as the solution itself. “This was the first time that information from multiple satellites was used to look at pollutants in the lower atmosphere,” Edwards says. “In the 1980s, we thought it would be great if we could measure levels of carbon monoxide from space. Now, with MOPITT, we can study carbon monoxide in the lower atmosphere and see how it moves around.”

Not only is carbon monoxide is an important indicator of pollution from biomass burning, but it also indicates pollutants emitted by industrial processes in urban regions. Having satellites that can peer through many kilometers of upper atmosphere and measure concentrations of trace pollutants in the lower atmosphere will have many applications in the future, such as monitoring the effects of chemical spills, industrial accidents and environmental phenomena on the atmosphere. Currently, his team is examining data collected from the wildfires of Colorado last summer and is also monitoring the atmospheric transport of industrial pollutants from China across the Pacific to the western United States.

Tim Palucka
Geotimes contributing writer

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